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Standard Practices for Detecting Susceptibility to Intergranular Attack in Austenitic Stainless Steels
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STANDARD published on 1.9.2021
Designation standards: ASTM A262-15(2021)
Publication date standards: 1.9.2021
SKU: NS-1036723
The number of pages: 20
Approximate weight : 60 g (0.13 lbs)
Country: American technical standard
Category: Technical standards ASTM
This specification covers the standard practices for detecting susceptibility to intergranular attack in austenitic stainless steels. These practices include five intergranular corrosion tests, namely: (1) oxalic acid etch test for classification of etch structures of austenitic stainless steels; (2) ferric sulfate-sulfuric acid test, (3) nitric acid test and (4) copper-copper sulfate-sulfuric acid test for detecting susceptibility to intergranular attack in austenitic stainless steels; and (5) copper-copper sulfate-50% sulfuric acid test for detecting susceptibility to intergranular attack in molybdenum-bearing cast austenitic stainless steels. Methods for preparing the test specimens, rapid screening tests, apparatus setup and testing procedures, and calculations and report contents are described for each testing practice. The etch structure types used to classify the specimens are: step structure, dual structure, ditch structure, isolated ferrite, interdendritic ditches, end-grain pitting I, and end-grain pitting II.
Keywords:
austenitic stainless steel, copper sulfate, corrosion testing, etch structures, ferric sulfate, intergranular corrosion, nitric acid, oxalic acid,, ICS Number Code 77.140.20 (Steels of high quality)
Significance and Use | ||||||||||||||
6.1?Use of the etch test allows rapid acceptance of specific lots of material without the need to perform time-consuming and costly hot acid immersion tests on those lots. |
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1. Scope | ||||||||||||||
1.1?These practices cover the following five tests: 1.1.1?Practice AOxalic Acid Etch Test for Classification of Etch Structures of Austenitic Stainless Steels (Sections 4 to 13, inclusive), 1.1.2?Practice BFerric Sulfate-Sulfuric Acid Test for Detecting Susceptibility to Intergranular Attack in Austenitic Stainless Steels (Sections 14 to 25, inclusive), 1.1.3?Practice CNitric Acid Test for Detecting Susceptibility to Intergranular Attack in Austenitic Stainless Steels (Sections 26 to 36, inclusive), 1.1.4?Practice ECopperCopper SulfateSulfuric Acid Test for Detecting Susceptibility to Intergranular Attack in Austenitic Stainless Steels (Sections 37 to 46, inclusive), and 1.1.5?Practice FCopperCopper Sulfate50 % Sulfuric Acid Test for Detecting Susceptibility to Intergranular Attack in Molybdenum-Bearing Austenitic Stainless Steels (Sections 47 to 58, inclusive). 1.2?The Oxalic Acid Etch Test is a rapid method of identifying, by simple etching, those specimens of certain stainless steel grades that are essentially free of susceptibility to intergranular attack associated with chromium carbide precipitates. These specimens will have low corrosion rates in certain corrosion tests and therefore can be eliminated (screened) from testing as acceptable. The etch test is applicable only to those grades listed in the individual hot acid tests and classifies the specimens either as acceptable or as suspect. 1.3?The ferric sulfate-sulfuric acid test, the coppercopper sulfate50 % sulfuric acid test, and the nitric acid test are based on weight loss determinations and, thus, provide a quantitative measure of the relative performance of specimens evaluated. In contrast, the coppercopper sulfate16 % sulfuric acid test is based on visual examination of bend specimens and, therefore, classifies the specimens only as acceptable or nonacceptable. 1.4?The presence or absence of intergranular attack in these tests is not necessarily a measure of the performance of the material in other corrosive environments. These tests do not provide a basis for predicting resistance to forms of corrosion other than intergranular, such as general corrosion, pitting, or stress-corrosion cracking. Note 1:?See Appendix X1
for information regarding test selection.
1.5?The values stated in SI units are to be regarded as standard. The inch-pound equivalents are in parentheses and may be approximate. 1.6?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.7?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. |
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2. Referenced Documents | ||||||||||||||
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