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Standard Test Method for Heating Value of Gases in Natural Gas and Flare Gases Range by Stoichiometric Combustion
STANDARD published on 1.5.2013
Designation standards: ASTM D4891-13
Note: WITHDRAWN
Publication date standards: 1.5.2013
SKU: NS-29044
The number of pages: 6
Approximate weight : 18 g (0.04 lbs)
Country: American technical standard
Category: Technical standards ASTM
Keywords:
calorimeter, flare gas, heating value, natural gas, stoichiometric conversion, ICS Number Code 75.060 (Natural gas), 75.160.30 (Gaseous fuels)
Significance and Use | |
5.1 This test method provides an accurate and reliable procedure to measure the total heating value of a fuel gas, on a continuous basis, which is used for regulatory compliance, custody transfer, and process control. 5.2 Some instruments which conform to the requirements set forth in this test method can have response times on the order of 1 min or less and can be used for on-line measurement and control. 5.3 The method is sensitive to the presence of oxygen and nonparaffin fuels. For components not listed and composition ranges that fall outside those in Table 1 and Table 2, modifications in the method and changes to the calibration gas or gasses being used may be required to obtain correct results. |
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1. Scope | |
1.1 This test method covers the determination of the heating value of natural gases and similar gaseous mixtures within the range of composition shown in Compound |
Concentration Range, mole, % |
Helium |
0.01 to 5 |
Nitrogen |
0.01 to 20 |
Carbon dioxide |
0.01 to 10 |
Methane |
50 to 100 |
Ethane |
0.01 to 20 |
Propane |
0.01 to 20 |
n-butane |
0.01 to 10 |
isobutane |
0.01 to 10 |
n-pentane |
0.01 to 2 |
Isopentane |
0.01 to 2 |
Hexanes and heavier |
0.01 to 2 |
Compound
CAS Number
Volatile Analytes
Acetone
67-64-1
Acetonitrile
75-05-8
Acrolein
107-05-8
Acrylonitrile
107-13-1
Benzene
71-43-2 2
1,3-Butadiene
106-99-0
Carbon disulfide
75-15-0
Chlorobenzene
108-90-7
Cumene (isopropylbenzene)
98-82-8
1,2-Dibromoethane
106-93-4
Ethylbenzene
100-41-4 2,2,4
Hexane
110-54-3
Methanol
67-56-1
Methyl isobutyl ketone
108-10-1
Methyl t-butyl ether
1634-04-4
Methylene chloride
75-09-2
Nitrobenzene
98-95-3
Nitropropane
79-46-9
Pentane2
109-66-0
Styrene
100-42-5
Tetrachloroethene
127-18-4
Toluene
108-88-3
Trichloroethene
79-01-6
Trimethylpentane
2 540-84-1
Xylenes (mixed isomers)
1330-20-7
Trimethylpentane
2 540-84-1
Xylenes (mixed isomers)
1330-20-7
Semi-volatile Analytes
Acenaphthene
83-32-9
Acenaphthylene
208-96-8
Aniline
62-53-3
Anthracene
120-12-7
Benzidine1
92-87-5
Benz[a]anthracene
56-55-3
Benzo[b]fluoranthene
205-99-2
Benzo[k]fluoranthene
207-08-9
Benzo[g,h,i]perylene
191-24-2
Benzo[a]pyrene
50-32-8
Benzo[e]pyrene2
192-97-2
Biphenyl2,
92-52-4
Cresol (mixed isomers)
1319-77-3
Chrysene
218-01-9
Dibenz[a,h]anthracene
53-70-3
Dibenzofuran
132-64-9
Dibenzo(a,e)pyrene
192-65-4
3,3’- Dimethoxybenzidine
119-90-4
Dimethylaminobenzene
60-11-7
7,12-Dimethylbenz(a)anthracene
57-97-6
3,3’- Dimethylbenzidine
119-93-7
á,á- Dimethylphenethylamine
122-09-8
2,4-Dimethylphenol
105-67-9
Fluoranthene
206-44-0
Fluorene
86-73-7
Indeno(1,2,3-cd)pyrene
193-39-5
Isophorone
78-59-1
3-Methylcholanthrene
56-49-5
2-Methylnaphthalene
91-57-6
Naphthalene
91-20-3
Perylene2
198-55-0
Phenanthrene
85-01-8
Phenol
108-95-2
1,4-Phenylenediamine
106-50-3
Pyrene
129-00-0
o-Toluidine
95-53-4
Aldehydes
Methanol
67-56-1
Formaldehyde
50-00-0
Acetaldehyde
75-07-0
Propanal
123-38-6
C1 to C5 Hydrocarbons
Description
Compound
CAS Number
C1 Alkanes
Methane
74-82-8
C2 Alkanes
Ethane
74-84-0
C3 Alkanes
Propane
74-98-6
C4 Alkanes
n-Butane
106-97-8
Isobutane
75-28-5
C5 Alkanes
n-Pentane
109-66-0
2-Methylbutane
78-78-4
Cyclopentane
287-92-3
C2 Olefins
Ethylene
74-85-1
C2 Alkanes
Acetylene
74-86-2
C3 Olefins
Propylene
115-07-1
C4 Olefins
1-Butene
106-98-9
2-Butene
107-01-7
Isobutene
115-11-7
C5 Olefins
1-Pentene
109-67-1
Cis-2-pentene
627-20-3
Trans-2-pentene
646-04-8
2-Methyl-1-butene
563-46-2
3-Methyl-1-butene
563-45-1
2-Methyl-2-butene
513-35-9
Cylcopentene
142-29-0
C3 Alkadienes
Propadiene
463-49-0
C4 Alkadienes
1,2-Butadiene
590-19-2
1,3-Butadiene
106-99-0
C5 Alkadienes
1,2-Pentadiene
591-95-7
1-cis-3-Pentadiene
1574-41-0
1-trans-3- Pentadiene
2004-70-8
1,4-Pentadiene
591-93-5
2,3-Pentadiene
591-96-8
3-Methyl-1,2- butadiene
598-25-4
2-Methyl-1,3- butadiene
78-79-5
Cyclopentadiene
542-92-7
Heating Value Range
Unit
Lower
Upper
Btu/ft3
83
2350
Standard Test Method for Calorific (Heating) Value of Gases in Natural Gas Range by Continuous Recording Calorimeter |
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Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method |
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EPA-600 /2-85-106 |
Evaluation of the Efficiency of Industrial Flares: Flare Head Design and Gas Composition |
Historical
1.6.2014
Historical
1.6.2014
Historical
1.11.2011
Historical
1.12.2008
Historical
1.11.2012
Historical
1.6.2011
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